| 36 Quotas as follows |
| 2011 UIPM World Cup Final |
| 08-10.07.2011 London (GBR) |
| Lena Schoeneborn (GER) |
| 2011 Asian/Oceania Championships |
| 19-22.05.2011 Chengdu (CHN) |
| Chen Qian (CHN) |
| Miao Yihua (CHN) |
| Yang Soo-jin (KOR) |
| Shino Yamanaka (JPN) |
| Narumi Kurosu (JPN) |
| Chloe Esposito (AUS) |
| African Championship |
| 22.24.07.2011 Cairo (EGY) |
| Aya Medany (EGY) |
| European Championship |
| 28.07-01.08.2011 Medway (GBR) |
| Adrienn Toth (HUN) |
| Victoria Tereshuk (UKR) |
| Amelie Caze (FRA) |
| Laura Asadauskaite (LTU) |
| Elena Rublevska (LAT) |
| Sarolta Kovacs (HUN) |
| Freyja Prentice (GBR) |
| Ekaterina Khuraskina (RUS) |
| 2011 World Modern Pentathlon Championships |
| 08-14.09.2011 Moscva (RUS) |
| Evdokia Gretchichnikova (RUS) |
| Elodie Clouvel (FRA) |
| Yane Marques (BRA) |
| 2011 Pan American Games |
| 15-16.10.2011 Guadalajara (MEX) |
| Margaux Isaksen (USA) |
| Tamara Vega (MEX) |
| Melanie McCann (CAN) |
| Pamela Zapata (ARG) |
| 2012 World Modern Pentathlon Championships |
| 07-13.05.2012 Roma (ITA) |
| Mhairi Spence (GBR) |
| Anastasia Prokopenko (BLR) |
| Annika Schleu (GER) |
| Pentathlon world ranking 01.06.2012 |
| 7 |
| Invitational places |
| 2 |
| Total 36 |
LTU
GBR
BRA
USA
CHN
BLR
AUS
LAT
IRL
UKR
CAN
POL
GER
EGY
RUS
FRA
HUN
CZE
KOR
ITA
JPN
MEX